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Application of chemiluminescence for the detection of peroxy compounds in high-performance liquid chromatography
Stefan Baj1, Anna Chrobok, Mariola Cieślik
1Institute of Organic Chemistry and Technology, Silesian University of Technology, Krzywoustego 4, 44-100, Gliwice, Poland. baj@polsl.gliwice.pl
Analytical and Bioanalytical Chemistry
|February 1, 2003
Abstract:
The possibility of applying post-column reaction and chemiluminescence to determine organic peroxy compounds by RP-HPLC was investigated. Conditions of qualitative and quantitative analyses have been established. The applicability of the method has been demonstrated for a series of compounds representative of the most important groups of peroxy-type compounds, that is, hydroperoxides, dialkyl peroxides, diacyl peroxides, peroxyesters, and peroxyacids.