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A new metal-organic open framework consisting of threefold parallel interwoven (6,3) nets
Myunghyun Paik Suh1, Hye Jin Choi, Soon Mog So
1School of Chemistry and Molecular Engineering, Center for Molecular Catalysis, Seoul National University, Seoul 151-747, Republic of Korea. mpsuh@plaza.snu.ac.kr
Inorganic Chemistry
|February 4, 2003
Abstract:
Threefold parallel interwoven (6,3) nets were assembled from Ni(II) cyclam complex and 1,3,5-tris[2-(4-carboxyphenyl)-1-ethynyl]benzene. The network generates triangular voids of effective size ca. 18.4 x 14.7 x 9.5 A. It contains 35% free volume of the crystal volume and is stable up to 300 degrees C.