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Updated: Sep 27, 2026

The Synthesis, Characterization and Reactivity of a Series of Ruthenium N-triphosPh Complexes
Published on: April 10, 2015
Photochemical and thermal ligand exchange in a ruthenium(II) complex based on a scorpionate terpyridine ligand
Emma R Schofleld1, Jean-Paul Collin, Nathalie Gruber
1Laboratoire de Chimie Organo-Minérale, UMR 7513 du CNRS, Université Louis Pasteur, Faculté de Chimie, 4, rue Blaise Pascal, 67070 Strasbourg Cedex, France.
Abstract:
A ruthenium(II) complex containing a 1,10-phenanthroline unit and a terpyridine fragment covalently linked to a benzonitrile group has been synthesised; coordination and decoordination of the benzonitrile group can be induced thermally and photochemically respectively, in an acetone-water mixture.
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