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Unusual reaction of chloramine-T with araldoximes
V Padmavathi1, K Venugopal Reddy, A Padmaja
1Department of Chemistry, Sri Venkateswara University, Tirupathi 517502, India. vkpuram2001@yahoo.com
The Journal of Organic Chemistry
|February 15, 2003
Abstract:
Reaction of araldoximes with 4 equiv of chloramine-T in refluxing methanol produces N-(p-tolyl)-N-(p-tosyl)benzamides via addition of 2 equiv of chloramine-T to the intermediate nitrile oxide followed by extrusion of sulfur dioxide.