Related Experiment Videos
Novel, stereoselective tricyclization of a dienyne by titanium aryloxide centers
Richard A Himes1, Phillip E Fanwick, Ian P Rothwell
1Department of Chemistry, Purdue University, 1393 Brown Building, West Lafayette, IN 47907-1393, USA.
Abstract:
Titanium centers supported by aryloxide ligation mediate the tricyclization of a dienyne via intramolecular insertion of an olefin into the titanium-vinyl bond of a titanacyclopent-2-ene.