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Enantioselective total synthesis of (-)-heliannuol A
Hidetoshi Kishuku1, Mitsuru Shindo, Kozo Shishido
1Institute for Medicinal Resources, University of Tokushima, 1-78 Sho-machi, Tokushima 770-8505, Japan.
Chemical Communications (Cambridge, England)
|March 5, 2003
Abstract:
An efficient and enantiocontrolled total synthesis of (-)-heliannuol A has been accomplished by employing ring closing metathesis and sequential diastereoselective epoxidation and regioselective reductive cleavage of the epoxide ring.