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Haiqing Peng1, Paul Reverdy, Valery N Khabashesku

  • 1Department of Chemistry, Rice Quantum Institute and Center for Nanoscale Science and Technology, Rice University, 6100 Main Street, Houston, Texas 77005-1892, USA.

Chemical Communications (Cambridge, England)
|March 5, 2003
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Diols are compounds with two hydroxyl groups. In addition to syn dihydroxylation, diols can also be synthesized through the process of anti dihydroxylation. The process involves treating an alkene with a peroxycarboxylic acid to form an epoxide. Epoxides are highly strained three-membered rings with oxygen and two carbons occupying the corners of an equilateral triangle. This step is followed by ring-opening of the epoxide in the presence of an aqueous acid to give a trans diol.