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Total synthesis and stereochemistry of (-)-cacospongionolide F
Damtew Demeke1, Craig J Forsyth
1Department of Chemistry, University of Minnesota, 207 Pleasant Street SE, Minneapolis, Minnesota 55455, USA.
Organic Letters
|March 28, 2003
Abstract:
[reaction: see text] The most recently described member of the cacospongionolide class of marine natural products has been assembled using a diastereochemically divergent total synthesis strategy that independently establishes the complete stereochemistry of cacospongionolide F and provides a new entry toward expansion of this phospholipase A(2) inhibitor chemotype.