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A novel concept to activate enediynes for DNA cleavage
Michael Schmittel1, Giampietro Viola, Francesco Dall'Acqua
1FB 8-OC1 (Chemie-Biologie), Universität Siegen, Adolf-Reichwein-Str, D-57068 Siegen, Germany. schmittel@chemie.uni-siegen.de
Chemical Communications (Cambridge, England)
|April 3, 2003
Abstract:
A novel concept is presented to activate enediynes via a biscumulenic intermediate using photoinduced electron transfer (PET).