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Cross section for the H+H2O abstraction reaction: experiment and theory
M Brouard1, I Burak, S Marinakis
1The Physical and Theoretical Chemistry Laboratory, The Department of Chemistry, University of Oxford, South Parks Road, Oxford, OX1 3QZ, United Kingdom.
Physical Review Letters
|April 12, 2003
Abstract:
The absolute value of the cross section for the abstraction reaction between fast H atoms and H2O has been determined experimentally at a mean collision energy of 2.46 eV. The OH population distribution at the same mean energy has also been determined. The new measurements are compared with state-of-the-art quantum mechanical and quasiclassical scattering calculations on the most recently developed potential energy surface.