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The Synthesis, Characterization and Reactivity of a Series of Ruthenium N-triphosPh Complexes
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Direct ion exchange of tris(2,2'-bipyridine)ruthenium(II) into an alpha-zirconium phosphate framework

Angel A Martí1, Jorge L Colón

  • 1Department of Chemistry, P.O. Box 23346, University of Puerto Rico, Río Piedras, Puerto Rico 00931.

Inorganic Chemistry
|April 29, 2003
PubMed

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Radical Substitution: Hydrogenolysis of Alkyl Halides with Tributyltin Hydride01:26

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Radical substitution reactions can be used to remove functional groups from molecules. The hydrogenolysis of alkyl halides is one such reaction, where the weak Sn–H bond in tributyltin hydride reacts with alkyl halides to form alkanes. Here, the reagent Bu3SnH yields tributyltin halide as a byproduct.
The bonds formed in this reaction are stronger than the bonds broken, making it energetically favorable. The reaction follows a radical chain mechanism similar to radical halogenation reactions,...