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Isonicotinate-functionalized cross-shaped tetrameric Ce(III)-containing arsenotungstate as a heterogeneous catalyst

Wenqiang Xia1, Cui Li1, Jinkun Li1

  • 1Jiangxi Key Laboratory for Mass Spectrometry and Instrumentation, School of Chemistry and Materials Science, East China University of Technology, Nanchang, 330013, China. erick@ecut.edu.cn.

Chemical Communications (Cambridge, England)
|September 29, 2026
PubMed

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Treating arylamines with nitrous acid gives aryldiazonium salts that are effective substrates in nucleophilic aromatic substitution reactions. The diazonio group in these salts can be easily displaced by different nucleophiles, yielding a wide variety of substituted benzenes. The leaving group departs as nitrogen gas, and this easy elimination is the driving force for the substitution reaction.
In the Sandmeyer reaction, for example, the diazonio group is replaced by a chloro, bromo, or cyano...