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Updated: Sep 26, 2026
Thermochemical Studies of Ni(II) and Zn(II) Ternary Complexes Using Ion Mobility-Mass Spectrometry
Published on: June 8, 2022
trans-Diaquabis(thiosemicarbazido-kappa2N,S)nickel(II) dimaleate dihydrate
Sheng-Li Li1, Anwar Usman, Ibrahim A Razak
1Department of Applied Chemistry, University of Science and Technology of China, Hefei 230026, People's Republic of China.
Abstract:
In the title compound, [Ni(CH(5)N(3)S)(2)(H(2)O)(2)](C(4)H(3)O(4))(2).2H(2)O, the Ni atom lies on a center of symmetry and is coordinated by N and S atoms from two thiosemicarbazide ligands and the O atoms of two water molecules in a distorted octahedral geometry. In the asymmetric unit, the three components are linked together by one O-H...O and two N-H...O hydrogen bonds. The packing is built from molecular ribbons parallel to the b direction, stabilized by intramolecular hydrogen bonds, and by one N-H...S and two N-H...O intermolecular hydrogen bonds. The ribbons are further connected into columns by N-H...O interactions and then into a three-dimensional network by three O-H...O hydrogen bonds.
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