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"Magic rod" rotaxanes: the hydrogen bond-directed synthesis of molecular shuttles under thermodynamic control
Jeffrey S Hannam1, Timothy J Kidd, David A Leigh
1School of Chemistry, University of Edinburgh, The Kings Buildings, West Mains Road, Edinburgh EH9 3JJ, United Kingdom.
Organic Letters
|May 24, 2003
Abstract:
[reaction: see text] Peptide [2]- and [3]rotaxanes are assembled in high yields under thermodynamic control using hydrogen bonding interactions and reversible cross olefin metathesis.