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Himeradine A, a novel C27N3-type alkaloid from Lycopodium chinense
Hiroshi Morita1, Yusuke Hirasawa, Jun'ichi Kobayashi
1Graduate School of Pharmaceutical Sciences, Hokkaido University, Sapporo 060-0812, Japan.
The Journal of Organic Chemistry
|May 24, 2003
Abstract:
A novel C(27)N(3)-type Lycopodium alkaloid consisting of a fastigiatine-type skeleton (C(16)N(2)) and a quinolizidine moiety (C(11)N), himeradine A (1), has been isolated from the club moss Lycopodium chinense, and the structure and relative stereochemistry were elucidated on the basis of spectroscopic data.