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Ni(III) vs. Ni(II)-thiyl radical: charge-delocalisation in a binuclear Ni(III)Ni(II)-dithiolate complex
Neil D J Branscombe1, Andrew J Atkins, Armando Marin-Becerra
1School of Chemistry, The University of Nottingham, Nottingham, UK NG7 2RD.
Chemical Communications (Cambridge, England)
|May 30, 2003
Abstract:
Multi-frequency EPR spectroscopy on 61Ni-labelled samples of [Ni2(L)]3+ confirms extensive charge-delocalisation between the Ni(III) centre and thiolate donors in the Ni(II)Ni(III) complex.