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Divalent europium formamidinates: synthesis, structures, EPR and luminescence properties
Zhifang Guo1, Glen B Deacon2, Toby D M Bell2
1College of Science & Engineering, James Cook University, Townsville 4811, QLD, Australia. peter.junk@jcu.edu.au.
Abstract:
Divalent europium formamidinate complexes [Eu(DFForm)2(py)3] (1) and [Eu(DippForm)2(py)3]·3py (2) were synthesized by the direct reaction of europium metal with N,N'-bis(2,6-difluorophenyl)formamidine (DFFormH) or N,N'-bis(2,6-diisopropylphenyl)formamidine (DippFormH) in pyridine (py) at room temperature. This straightforward one-step approach from the free metal avoids the need for heating and the use of redox transmetallation organometallic reagents. Single-crystal X-ray diffraction reveals seven-coordinate EuII in both complexes. In addition, a hexanuclear europium(III) cage, [Eu6(DFForm)6F4O4(py)6] (3), featuring alternating μ-fluoride and μ-oxide bridges, was structurally characterized. The electron paramagnetic resonance (EPR) and photoluminescence properties of complex 1 were investigated. EPR spectra are consistent with an 8S7/2 ground state and hence the Eu(II) formulation. Compound 1 exhibits characteristic EuII 4f65d1 → 4f7 emission in THF solution at room temperature, with a broad emission band centred at 460 nm, a luminescence quantum yield of 0.043 and lifetime of 5.7 ns.
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