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Sensitised near-infrared emission from lanthanides using a covalently-attached Pt(II) fragment as an antenna group
Nail M Shavaleev1, Lucy P Moorcraft, Simon J A Pope
1School of Chemistry, University of Bristol, Cantock's Close, Bristol, UK BS8 1TS.
Abstract:
In a series of heterodinuclear complexes in which a Pt(PPh3)2(catecholate) chromophore is covalently linked to a lanthanide tris(diketonate) unit, sensitised near-IR emission from Yb(III), Nd(III) and Er(III) occurs on excitation of the Pt(II) chromophore at 520 nm.
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