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Trimethyltriazacyclohexane as bridging ligand for triangular Cu3 units and C-H hydride abstraction into a Cu6 cluster
Randolf D Köhn1, Zhida Pan, Mary F Mahon
1Department of Chemistry, University of Bath, Bath, UK BA2 7AY. r.d.kohn@bath.ac.uk
Chemical Communications (Cambridge, England)
|June 18, 2003
Abstract:
Reaction of [Cu(MeCN)4](BF4) with N,N',N"-trimethyl-1,3,5-triazacyclohexane in CH2Cl2 leads to two Cu6 clusters containing the triazacyclohexane as a ligand to triangular Cu3 units with the abstraction and incorporation of chloride and hydride.