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Molecular tectonics: from enantiomerically pure sugars to enantiomerically pure triple stranded helical coordination
Philippe Grosshans1, Abdelaziz Jouaiti, Véronique Bulach
1Laboratoire de Chimie de Coordination Organique, Institut Le Bel, Université Louis Pasteur, 4, rue Blaise Pascal, 67000 Strasbourg, France.
Chemical Communications (Cambridge, England)
|July 5, 2003
Abstract:
The self-assembly between a bis-monodentate tecton based on two pyridine units connected to an enantiomerically pure isomannide stereoisomer and HgCl2 leads to the formation of an enantiomerically pure triple stranded helical infinite coordination network which was structurally characterised by X-ray diffraction on single crystal.