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Updated: Jul 20, 2025

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Published on: March 19, 2020
1-D and 2-D coordination networks based on tetrathiacalix[]arene derivative generated with mercury and cobalt salts
Huriye Akdaş-Kiliç1,2, Ernest Graf3, Mir Wais Hosseini3
1Department of Chemistry, Yıldız Technical University, İstanbul, Turkey.
Abstract:
The combination of four iso-nicotinate appended tetrathiacalix[4]arene (TCA-1) in 1,2-alternate imposed conformation behaving as neutral tectons with Co(II)Cl2 and Hg(II)Cl2 metallic salts, leads to the formation of neutral, new coordination networks. Indeed, the tetrasubstituted TCA-1 derivative leads to a 1D coordination polymer with Co(II)Cl2 and a 2D grid-like network with, Hg(II)Cl2. The effect of the nature of the metal used on the dimensionality was demonstrated by X-ray diffraction studies on a single crystal.
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