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Updated: Jul 20, 2025
Synthesis of a Thiol Building Block for the Crystallization of a Semiconducting Gyroidal Metal-sulfur Framework
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New 2-D silver(I) coordination network constructed from thiomethyl group-substituted p-tert-butylthiacalix[]arene
Huriye Akdaş-Kiliç1,2, Ernest Graf3, Mir Wais Hosseini3
1Department of Chemistry, Yıldız Technical University, İstanbul, Turkey.
Abstract:
New ligand based on p-tertbutyltetrathiacalix[4]arene blocked in 1,3-alternate conformation, was achieved via a multistep synthesis with the introduction of thiomethylpropoxy groups on the lower rim which leads to a neutral tecton. The combination of this p-tertbutyltetrathiacalix[4]arene (-TCA-2), in 1, 3-alternate imposed conformation, with tetrahedral Ag(I)SbF6 salt, leads to the formation of neutral, new 2-D coordination network, which was structurally investigated in the solid state by X-ray diffraction methods on a single crystal.
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