Related Experiment Videos
In situ complexation of lithium chloride by amphiprotic cyclophosphazenes
Philip I Richards1, Mark A Benson, Alexander Steiner
1Department of Chemistry, University of Liverpool, Crown Street, Liverpool, UK L69 7ZD.
Chemical Communications (Cambridge, England)
|July 5, 2003
Abstract:
The amphiprotic cyclophosphazene [CH3O(CH2)3NH]6P3N3 (1) incorporates lithium chloride via successive protonation with HCl and deprotonation with Bu(n)Li (or vice versa) to generate the coordination polymer 1.2LiCl, a molecular model compound for lithium ion containing solid polymer electrolytes.