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A new, unexpected synthesis of 1,3-dithietanones
Béatrice Quiclet-Sire1, Graciela Sanchez-Jimenez, Samir Z Zard
1Laboratoire de Synthèse Organique associé au CNRS, Ecole Polytechnique, 91128 Palaiseau, France.
Chemical Communications (Cambridge, England)
|July 5, 2003
Abstract:
Treatment of a geminal pivaloxy xanthate, prepared by an intermolecular radical addition of a xanthate to vinyl pivalate, gives a 1,3-dithietanone, a little known class of compounds.