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Separated local field spectroscopy of columnar and nematic liquid crystals
Sergey V Dvinskikh1, Herbert Zimmermann, Arnold Maliniak
1Division of Physical Chemistry, Arrhenius Laboratory, Stockholm University, SE-10691 Stockholm, Sweden. sergey@physc.su.se
Abstract:
We are in this work comparing the efficiencies of various 1H-13C separated local field (SLF) experiments when applied to columnar and nematic liquid crystals. In particular, the performances of the conventional SLF, proton-detected local field (PDLF), and polarization inversion spin exchange at the magic angle (PISEMA) methods in terms of spectral resolution, robustness, and ability to measure long-range couplings are investigated. The PDLF sequence provides in most cases the best dipolar resolution. This is especially obvious for weakly coupled 1H-13C spin pairs.