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Updated: Jul 31, 2026

Preparation and Use of Carbonyl-decorated Carbenes in the Activation of White Phosphorus
Published on: October 3, 2014
Engineering carbene rearrangements in crystals: from molecular information to solid-state reactivity
1Department of Chemistry and Biochemistry, University of California, Los Angeles, California 90095-1569, USA. mgg@chem.ucla.edu
Abstract:
Although severely restricted, reactions in crystals have delivered some of the most impressive examples of chemical control and provided an ideal medium for detailed mechanistic studies. However, to take full advantage of their potential and avoid their shortcomings, a systematic approach for the reliable design of reaction in crystals is required. To that end, strategies based on structural and energetic information contained at the molecular level have been explored with reactions involving carbene rearrangements.
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