Direct formation of an organonitrogen compound from a molybdenum nitrido species
Huub Henderickx1, Gerard Kwakkenbos, Alexander Peters
1DSM Research, P.O. Box 18, 6160MD Geleen, The Netherlands.
Chemical Communications (Cambridge, England)
|August 26, 2003
Abstract:
The molybdenum nitrido complex 15NMo[N(R)Ar]3 (where R = C(CD3)2CH3, Ar = 3,5-C6H3Me2) reacted with the anhydride of trifluoroacetic acid at room temperature to afford the correspondent organonitrogen compound in almost quantitative yield without the necessity of using additional reagents to achieve the C-N coupling.
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