Related Experiment Videos
Homoatomic P --> P coordination: a versatile synthetic approach to polyphosphorus dications
Neil Burford1, Paul J Ragogna, Robert McDonald
1Department of Chemistry, Dalhousie University, Halifax, Nova Scotia, B3H 4J3, Canada. Neil.Burford@dal.ca
Chemical Communications (Cambridge, England)
|August 26, 2003
Abstract:
Polyphosphorus dications have been synthesised and comprehensively characterised as diphosphine (dppe, dmpe and dpph) linked Ar2P+ Lewis acids (Ar = C6H5); this application of unique homoatomic coordination chemistry provides important building blocks for extended systems.