[Self-assembly of nano-structured silver particle and its surface-enhanced Raman spectroscopic application]

Planar arrays of nano-structured silver particle were self-assembled on poly-lysine modified glass surfaces. SEM characterization indicates that silver particles were assembled as a sub-monolayer. A comparison of the UV/Vis spectra of silver colloid and the arrays demonstrates that the poly-lysine layer showed size selectivity for the self-assembling silver particles. Surface-enhanced FT-Raman spectrum of methylviolegen on the array reveals that Raman scattering in near IR region was mainly enhanced via a chemical enhancement mechanism.