Numerical study of colloidal suspensions of soft spherical particles using the network method. 2. AC electrokinetic...

The network simulation method is used to solve numerically the equation system that determines the dynamic electrophoretic mobility and the dielectric response of dilute suspensions of soft particles. This system was extensively studied theoretically by Ohshima (H. Ohshima, J. Colloid Interface Sci. 233 (2001) 142-152), who obtained analytical expressions for the static and dynamic electrophoretic mobility. However, the validity of his analytical result is restricted to relatively thick membranes with high drag coefficient and to relatively high electrolyte concentrations. As for the dielectric properties, there are only a few works dealing with particles without a core (ion exchange resins) and, to our knowledge, no numerical studies. Our theoretical model is basically similar to Ohshima's, except that we take into account the mechanical force acting on the surface of the core, which he neglects. The inclusion of this term is crucial when the general problem including arbitrary values of the parameters is analyzed. However, it has little bearing when the membrane is thick and the drag coefficient is high, so that our results for the electrophoretic mobility generally confirm Ohshima's equation when all the required conditions are met.