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Formation of pyrene nano-rods within a supramolecular framework
1Department of Chemistry, State University of New York at Buffalo, Buffalo, New York 14260-3000, USA.
Abstract:
The combination of trimesic acid and the tri-dentate linker 1,3,5-tri(4-pyridyl)-2,4,6-triazine leads to the assembly of a bilayer structure, which contains four pyrene molecules per cavity; adjacent tetrameric aggregates within the channels formed by the superimposed layers combine to yield pyrene nano-rods.