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A new route to furanoeremophilane sesquiterpenoids. Synthesis of (+/-)-6[small beta]-hydroxyeuryopsin
M Sundaram Shanmugham1, James D White
1Department of Chemistry, Oregon State University, Corvallis, Oregon 97331-4003, USA.
Chemical Communications (Cambridge, England)
|January 23, 2004
Abstract:
The naturally occurring furanoeremophilane 6[small beta]-hydroxyeuryopsin was synthesized by a novel route which involved Stille coupling of a 2-furylstannane with a cyclohexylmethyl bromide, followed by intramolecular formylation of the furan to complete the tricyclic nucleus of the sesquiterpenoid.
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