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Updated: Aug 19, 2026

Synthesis and Characterization of Supramolecular Colloids
Published on: April 22, 2016
Factors influencing solvent adduct formation by calixarenes in the solid state
Zouhair Asfari1, Alexander Bilyk, Cameron Bond
1E.C.P.M., Université Louis Pasteur de Strasbourg, 25 rue Becquerel, Cronenbourg 67087, Strasbourg Cedex 2, France.
Abstract:
Structural studies of seven very differently functionalised derivatives of calix[4]arene have been used to provide an analysis of the numerous factors which may influence solvent adduct formation by calixarenes. Evidence is presented that even where a solvent guest is included within the calixarene cavity, interactions solely within the cavity cannot be seen as the sole influences upon the guest position and orientation.
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