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Updated: Aug 29, 2026

Non-equilibrium Microwave Plasma for Efficient High Temperature Chemistry
Published on: August 1, 2017
Radiative opacities and configuration interaction effects of hot iron plasma using a detailed term accounting model
Fengtao Jin1, Jiaolong Zeng, Jianmin Yuan
1Department of Applied Physics, National University of Defense Technology, Changsha 410073, People's Republic of China.
Abstract:
We have calculated the radiative opacities of iron plasma in local thermodynamic equilibrium using a detailed term accounting model. The extensive atomic data are obtained by multiconfiguration Hartree-Fock (MCHF) method, with Breit-Pauli relativistic corrections. Extensive configuration interaction (CI) has been included based on LS coupling to obtain energy levels and the bound-bound transition cross sections. A detailed configuration accounting model is applied to evaluate the bound-free absorption cross sections. We simulate two experimental transmission spectra [G. Winhart et al., Phys. Rev. E 53, R1332 (1996); P. T. Springer et al., J. Quant. Spectrosc. Radiat. Transf. 58, 927 (1997)] to verify our calculation model, one is at a temperature of 22 eV and a density of 10(-2) g/cm(3) and the other is at a temperature of 20 eV and a lower density of 10(-4) g/cm(3). It is shown that the strong CI can effectively change the oscillator strengths in contrast to the single configuration HF method. For both of the two simulated transmission spectra good agreement is obtained between the present MCHF results and the experimental data. Spectrally resolved opacities and Planck and Rosseland mean opacities are also calculated. For the isothermal sequence of T=20 eV, when the density decreases from 10(-2) to 10(-5) g/cm(3), the linewidth also decreases so that the iron transition arrays show more discrete line structures and the linewidth becomes very important to the Rosseland mean opacity.
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