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![Cercosporin-Photocatalyzed [4+1]- and [4+2]-Annulations of Azoalkenes Under Mild Conditions](/_next/image?url=https%3A%2F%2Fcloudfront.jove.com%2FCDNSource%2Fteasers%2F60786.jpg&w=3840&q=50)
Cercosporin-Photocatalyzed [4+1]- and [4+2]-Annulations of Azoalkenes Under Mild Conditions
Published on: July 17, 2020
Two triclinic polymorphs of 2,3,5,6-tetrakis(naphthalen-2-ylsulfanylmethyl)pyrazine
Jessica Pacifico1, Helen Stoeckli-Evans
1Institut de Chimie, Université de Neuchâtel, Av. de Bellevaux 51, CP 2, CH-2007 Neuchâtel, Switzerland.
Abstract:
The title compound, C(48)H(36)N(2)S(4), can be crystallized as two polymorphic structures, (I) and (II), both of which are in the triclinic space group P-1 and possess C(i) symmetry. In the crystal structure of polymorph (I), the adjacent naphthalene moieties are orientated towards one another and are inclined to one another by 78.7 (1) degrees, resulting in weak C-H.pi interactions. In polymorph (II), the adjacent substituents are orientated away from one another, enclosing the pyrazine N atoms. In this way, the S atom of one substituent sits below the plane of the naphthalene ring of the other substituent.
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