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From metal to ligand electroactivity in nickel(II) oxamato complexes
Xavier Ottenwaelder1, Rafael Ruiz-García, Geneviève Blondin
1Laboratoire de Chimie Inorganique, Bât. 420, Université Paris-Sud, 91405 Orsay, France.
Chemical Communications (Cambridge, England)
|February 20, 2004
Abstract:
The locus of oxidation in square-planar nickel(ii) oxamato complexes can be continuously shifted from the metal to the ligand by an appropriate choice of electron-donating substituents on the aromatic moiety of the ligand.