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Updated: Aug 25, 2026

Free Radicals in Chemical Biology: from Chemical Behavior to Biomarker Development
Published on: April 15, 2013
Reactivity of beta-lactamido N-sulfonyl radicals
Florian Montermini1, Emmanuel Lacôte, Max Malacria
1Laboratoire de Chimie Organique, UMR CNRS 7611, Université Pierre et Marie Curie, Case 229, 4 Place Jussieu, 75005 Paris, France.
Abstract:
[reaction: see text] A new class of N-substituted radical has been studied. Obtained from the corresponding chlorides, beta-lactamido N-sulfonyl radicals were allylated and added onto electron-rich olefins. It has been shown that the radicals do not undergo desulfonylation and are electrophilic in nature.
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