Extractive phase vanishing reactions with dichloromethane, perfluorohexanes, and dibromoethane: slow addition in a
Dennis P Curran1, Stefan Werner
1Department of Chemistry, University of Pittsburgh, Pittsburgh, Pennsylvania 15260, USA. curran@pitt.edu
Abstract:
[reaction: see text] Partition coefficient measurements and experiments with a dye show that a new fluorous "phase vanishing reaction" described by Jana and Verkade occurs by an extractive mechanism. This mechanism is contrasted with the original diffusive phase-vanishing reactions introduced by Ryu and co-workers.
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