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Hyperconjugation effect in substituted methyl boranes: an orbital deletion procedure analysis

Yirong Mo1, Haijun Jiao, Paul von Ragué Schleyer

  • 1Department of Chemistry, Western Michigan University, Kalamazoo, Michigan 49008, USA. ymo@wmich.edu

The Journal of Organic Chemistry
|May 11, 2004
PubMed
Summary

Hyperconjugation in methyl boranes was quantified using orbital deletion. Stabilization energies ranged from 3.4 to 6.8 kcal/mol, influenced by substituent electronegativity and bonding competition.

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