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Using stereoelectronic effects to explain selective reactions of 4-substituted five-membered ring oxocarbenium ions
1Department of Chemistry, University of California-Irvine, Irvine, California 92697-2025, USA.
Organic Letters
|June 5, 2004
Abstract:
[reaction: see text] The utility of the inside attack model to predict and analyze the stereoselectivities of nucleophilic additions to complex five-membered ring oxocarbenium ions is demonstrated in a systematic study of C-4-substituted acetals.