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Updated: Aug 23, 2026

Imine Metathesis by Silica-Supported Catalysts Using the Methodology of Surface Organometallic Chemistry
Published on: October 18, 2019
Immobilization of Pd(OAc)(2) in ionic liquid on silica: application to sustainable Mizoroki-Heck reaction
Hisahiro Hagiwara1, Yoshitaka Sugawara, Kohei Isobe
1Graduate School of Science and Technology, Niigata University, 8050, 2-Nocho, Ikarashi, Niigata 950-2181, Japan. hagiwara@gs.niigata-u.ac.jp
Abstract:
[reaction: see text] Palladium acetate was supported on amorphous silica with the aid of an ionic liquid, [bmim]PF(6). The immobilized catalyst was highly efficient in promoting the Mizoroki-Heck reaction without a ligand in n-dodecane for at least six reuses, in 89 approximately 98% yields. The TON and TOF reached 68 400 and 8000, respectively.
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