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Functionalized thiosemicarbazone clusters of copper(I) and silver(I)
Laura J Ashfield1, Andrew R Cowley, Jonathan R Dilworth
1Inorganic Chemistry Laboratory, University of Oxford, South Parks Road, Oxford, OX1 3QR, UK.
Inorganic Chemistry
|July 9, 2004
Abstract:
Reaction of [Cu(MeCN)(4)](+) with thiosemicarbazones bearing groups such as phenol, pyridine, or ferrocene gives tetranuclear or hexanuclear clusters with functional substituents; analogous air stable fluorescent clusters can also be prepared with Ag(I).