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Bis[benzidinium(1-)] pentamolybdate.

Shu-Fang Zhang1, Yan-Qiong Sun, Guo-Yu Yang

  • 1Coordination and Hydrothermal Chemistry Group, State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, 350002, People's Republic of China.

Acta Crystallographica. Section C, Crystal Structure Communications
|July 9, 2004
PubMed
Summary
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A novel two-dimensional coordination polymer containing molybdenum-oxygen chains was synthesized. These layers are interconnected by organic cations through hydrogen bonding, forming a unique extended structure.

Area of Science:

  • Inorganic Chemistry
  • Materials Science
  • Crystallography

Background:

  • Coordination polymers offer diverse structural motifs and potential applications.
  • Molybdenum-oxygen clusters are versatile building blocks for novel materials.

Purpose of the Study:

  • To synthesize and characterize a new two-dimensional coordination polymer with a molybdenum-oxygen framework.
  • To elucidate the crystal structure and bonding interactions within the compound.

Main Methods:

  • Hydrothermal synthesis was employed for material preparation.
  • Single-crystal X-ray diffraction was used to determine the crystal structure.

Main Results:

  • A novel two-dimensional layer structure, [(Mo4O14)n]4n-, was successfully synthesized.

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  • The layers are linked by organic cations, [(C12H13N2)]+, via N-H...O hydrogen bonds.
  • The structure features [Mo4O14]4- clusters connected through MoO6 octahedra and MoO5 square-pyramidal vertices.

    • Conclusions:

    • The study reports the successful synthesis and structural determination of a new molybdenum-based coordination polymer.
    • The hydrogen bonding interactions play a crucial role in linking the inorganic layers and stabilizing the overall structure.