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Structural, magnetic and DFT studies of a hydroxide-bridged [Cr8] wheel

Paul Christian1, Gopalan Rajaraman, Andrew Harrison

  • 1Department of Chemistry, The University of Manchester, Oxford Road, Manchester, UK M13 9PL.

Dalton Transactions (Cambridge, England : 2003)
|July 15, 2004
PubMed

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Crystal Field Theory
To explain the observed behavior of transition metal complexes (such as colors), a model involving electrostatic interactions between the electrons from the ligands and the electrons in the unhybridized d orbitals of the central metal atom has been developed. This electrostatic model is crystal field theory (CFT). It helps to understand, interpret, and predict the colors, magnetic behavior, and some structures of coordination compounds of transition metals.
CFT focuses on...