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In Situ Synthesis of Gold Nanoparticles without Aggregation in the Interlayer Space of Layered Titanate Transparent Films
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Gold(I) or gold(III) as active species in AuCl(3)-catalyzed cyclization/cycloaddition reactions? A DFT study

Bernd F Straub1

  • 1Department Chemie der Ludwig-Maximilians-Universität, Butenandtstrasse 5-13 (Haus F), D-81377 Munich, Germany. Bernd.F.Straub@cup.uni-muenchen.de

Chemical Communications (Cambridge, England)
|July 28, 2004
PubMed

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Thermal cycloadditions are reactions where the source of activation energy needed to initiate the reaction is provided in the form of heat. A typical example of a thermally-allowed cycloaddition is the Diels–Alder reaction, which is a [4 + 2] cycloaddition. In contrast, a [2 + 2] cycloaddition is thermally forbidden.