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Structural characterization and luminescence behavior of a silver(I) 1D polymeric chain constructed via a Bridge with
Chih-Chieh Wang1, Cheng-Han Yang, Shih-Min Tseng
1Department of Chemistry, Soochow University, Taipei, Taiwan 111, R.O.C. ccwang@mail.scu.edu.tw
Abstract:
A new polymeric silver complex, [Ag(2)(L(2))(ClO(4))(2)] (L = 4,5-diazospirobifluorene), has been synthesized and shown to exhibit interesting luminescence properties in a single crystal. Structural analysis reveals a one-dimensional chain, which contains a [Ag(2)(L(2))](2+) dimer bridged with ClO(4)(-). The Ag...Ag distances are 2.776(1) and 4.575(1) A incorporated by two L ligands and by a ClO(4)(-) bridge, respectively.
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