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Engineering 'Golden' Fluorescence by Selective Pressure Incorporation of Non-canonical Amino Acids and Protein Analysis by Mass Spectrometry and Fluorescence
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Photoluminescent layered lanthanide silicates.

Duarte Ananias1, Mariya Kostova, Filipe A Almeida Paz

  • 1Contribution from the Department of Chemistry, CICECO, University of Aveiro, 3810-193 Aveiro, Portugal.

Journal of the American Chemical Society
|August 19, 2004
PubMed
Summary

New layered lanthanide silicates (AV-22 materials) were synthesized and characterized. These materials exhibit tunable photoluminescence, with potential applications as phosphors in lighting technologies.

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Area of Science:

  • Materials Science
  • Inorganic Chemistry
  • Solid-State Chemistry

Background:

  • Lanthanide silicates are a class of materials with interesting optical properties.
  • Developing novel phosphors with tunable emission is crucial for advanced lighting applications.

Purpose of the Study:

  • To hydrothermally synthesize and structurally characterize novel layered lanthanide silicates, designated AV-22.
  • To investigate the photoluminescent properties of these AV-22 materials doped with various lanthanide ions.

Main Methods:

  • Single-crystal and powder X-ray diffraction for structural elucidation.
  • Chemical analysis, thermogravimetry, SEM, (29)Si MAS NMR, and photoluminescence spectroscopy for characterization.
  • Hydrothermal synthesis technique.

Main Results:

  • Successful synthesis of K(3)[M(1-a)Ln(a)Si(3)O(8)(OH)(2)] (AV-22) materials.
  • Er-AV-22 functions as a room-temperature infrared phosphor.
  • Tb- and Eu-AV-22 exhibit visible emission with efficiencies comparable to commercial standards.
  • Tunable photoluminescence achieved by incorporating multiple lanthanide ions.
  • Evidence of Tb(3+)-to-Eu(3+) energy transfer in mixed-doped materials.

Conclusions:

  • The layered AV-22 structure facilitates the incorporation of multiple lanthanide ions for fine-tuning luminescence.
  • These materials show promise for applications in lighting and display technologies.
  • Efficient energy transfer mechanisms were observed in co-doped AV-22 materials.