Low-energy electron scattering cross section for the production of CO within solid films of carbon dioxide

We report absolute electron scattering cross sections sigma(p) for the production of CO within thin solid film of carbon dioxide (CO(2)) condensed on a solid Ar substrate. The CO fragments, which remain trapped within the bulk of the carbon dioxide film, are detected in situ by recording energy losses to their lowest triplet electronic state a (3)Pi using high-resolution electron-energy-loss spectroscopy. The production of CO is studied as a function of the electron exposure, film thickness, and incident electron energy between 2 and 30 eV, a range within which most of the secondary electrons are created in systems irradiated by high-energy particles. The energy dependence is characterized by a feature around 4 eV with sigma(p)=(7.0+/-4.0)x10(-18) cm(2), a minimum around 7 eV, a strong rise up to a large and broad maximum around 15 eV with sigma(p)=(5.4+/-2.5)x10(-17) cm(2), a decrease to a minimum around 18.5 eV, and finally a monotonous increase up to 30 eV. The CO production is discussed in terms of the formation of electron resonances or transient anion states, which may lead directly to the fragmentation of the molecule via dissociative electron attachment or indirectly by decaying into an entirely repulsive part of the corresponding excited neutral and positive ion states.