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C-H activation of ethers and alkanes by germylene-aryl halide complexes
Karla A Miller1, Jeffrey M Bartolin, Rory M O'Neill
1University of Michigan, Department of Chemistry, Ann Arbor, MI 48109, USA.
Abstract:
Regioselective, room-temperature C-H activation of alkanes and ethers by stable germylenes and aryl halides is reported. Germylenes, Ge[CH(SiMe3)2]2 and Ge[N(SiMe3)2]2, and aryl halides, PhI, PhBr, and PhCl, have been employed. High yields of C-H activation products can be obtained through the use of high-dilution techniques.
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