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Solution- and solid-state characterisation of a configurationally-stable beta-diketiminato-supported calcium primary
Anthony G Avent1, Mark R Crimmin, Michael S Hill
1The Chemistry Laboratory, University of Sussex, East Sussex BN1 9QJ, UK.
Dalton Transactions (Cambridge, England : 2003)
|October 16, 2004
Abstract:
'Selective' protonolysis of the beta-diketiminato calcium derivative [Ca[(NDippCMe)(2)CH][N(SiMe(3))(2)](THF)] Dipp = C(6)H(3)(i)Pr(2)-2,6) with H(2)N(CH(2))(2)OCH(3) produced the dimeric species [Ca[(NDippCMe)(2)CH][mu-NH(CH(2))(2)OMe]](2), which has been fully characterised in solution and in the solid state.